I've tried to locate the API or upload protocol for PWS and WU but haven't had any luck. Lots of outdated links and no obvious public access on their web sites. Makes it tough to know what they really expect. Based on the PWS web site, it would seem that the uploaded Pressure Type can be changed but that had no effect in my tests.
I've contacted PWS (AerisWeather) and will post back after a response.
Something else of interest concerning PWS for users of the plugin. Each PWS account allows for multiple weather stations. Each station has it's own ID and API Key. That key is advertised as required to upload data. However, the plugin connection fails if that key is used. The plugin requires the PSW Weather (account) password and Station ID (name).